Претрага
11 items
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Characterization of biochar surface functional groups
In this work, biochar originating from paper fibres was examined. Biochar was prepared via pyrolysis method at 550°C. Oxygen-containing functional groups on biochar surface were determined. The surface functional groups of biochar were analysed by Fourier transform infrared spectroscopy. The amount of oxygen-containing functional groups was performed with Boehm titration. The total acidity of biochar was mostly attributed to carboxylic and lactonic groups.Marija Ilić, Vesna Pavelkić, Aleksandar Lolić, Branko Leković. "Characterization of biochar surface functional groups" in Šesti Naučno-stručni skup Politehnika, Beograd, 10. decembar 2021., Beograd : Akademija tehničkih strukovnih studija (2021) М63
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Crystallographic, spectroscopic, thermal and computational studies of polymeric cobalt(II)–mellitate complex with 2,2′-bipyridine
Orange single crystals of new polymeric cobalt(II) complex {[Co(bipy)(H2O)4]2[Co(μ-mell)(H2O)2]·10H2O}n, 1, were synthesized by slow evaporation method at room temperature (bipy = 2,2′-bipyridine, mell = hexaanion of mellitic acid) and its crystal structure was determined by single-crystal X-ray diffraction. The complex 1 was characterized based on elemental analysis, FTIR spectroscopy and thermal (TG/DTA) analysis followed by computational analysis of noncovalent interactions and quantum chemical calculations of interaction energies. In 1, two crystallographically different Co(II) atoms adopt a deformed octahedral geometry, ...Lidija Radovanović, Dušan P. Malenov, Marko V. Rodić, Aleksandar Kremenović, Jelena Rogan. "Crystallographic, spectroscopic, thermal and computational studies of polymeric cobalt(II)–mellitate complex with 2,2′-bipyridine" in Journal of Molecular Structure, Elsevier BV (2021). https://doi.org/10.1016/j.molstruc.2021.132202 М22
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Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)
Jelena Pantić, Vladimir Urbanovich, Vesna Poharc-Logar, Bojan Jokić, Marija Stojmenović, Aleksandar Kremenović, Branko Matović (2014)Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the highpressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 °C, sphene undergoes into phase transition, from room-temperature phase P21/a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the ...Jelena Pantić, Vladimir Urbanovich, Vesna Poharc-Logar, Bojan Jokić, Marija Stojmenović, Aleksandar Kremenović, Branko Matović. "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)" in Physics and Chemistry of Minerals, Springer Science and Business Media LLC (2014). https://doi.org/10.1007/s00269-014-0693-x М22
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Adsorption and degradation of some psychiatric drugs by sol-gel synthesized titania-based photocatalysts: influence of tungsten and sodium content
Nina L. Finčur, Maja J. Šćepanović, Mirjana Grujić-Brojčin, Biljana F. Abramović, Jugoslav B. Krstić, Aleksandar Kremenović, Tatjana Srećković, Aleksandar Golubović (2019)Mesoporous anatase nanopowders were doped with 0.05−0.5 mol% of W6, in order to obtain more efficient photocatalyst than TiO2 Degussa P25 in the degradation of amitriptyline (AMI) under simulated solar irradiation (SSI). Dominant XRPD peaks were ascribed to anatase phase, with additional peaks which could correspond to brookite, TiO2 bronze and sodium titanate, Na2Ti9O19. The Raman scattering measurements have confirmed anatase as dominant phase, with broad Raman feature at ~270 cm−1 possibly related to Ti–O–Na stretching vibration. All W-doped ...Sol-gel synthesis, Doped titania nanopowders, XRPD, Raman spectroscopy, Adsorption and photocatalytic degradation, Psychiatric drugsNina L. Finčur, Maja J. Šćepanović, Mirjana Grujić-Brojčin, Biljana F. Abramović, Jugoslav B. Krstić, Aleksandar Kremenović, Tatjana Srećković, Aleksandar Golubović. "Adsorption and degradation of some psychiatric drugs by sol-gel synthesized titania-based photocatalysts: influence of tungsten and sodium content" in Journal of Sol-Gel Science and Technology, Springer Science and Business Media LLC (2019). https://doi.org/10.1007/s10971-019-04925-4 М21
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A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra
Tamara Đorđević, Ljiljana Karanović (2010)A new monoclinic polymorph of Ba(AsO3OH) was synthesized under hydrothermal conditions. It represents a previously unknown structure type. Its crystal structure was determined from a racemic twin using single-crystal X-ray diffraction data collected at 120 and 293 K [space group P21, a=7.2149(14)/7.2370(2), b=7.7028(15)/7.7133(2), c=21.7385(43)/21.8079(5) Å, β=95.95(3)/96.073(1)1, V=1201.6(4)/1210.51(5) Å3, Z=12]. The crystal structure of P21-Ba(AsO3OH) has a layered character and is built up of four types of regularly alternating layers parallel to (0 0 1). Every AsO3OH tetrahedron is chelating to two Ba atoms and ...Ba(AsO3OH), хидротермална синтеза, структурна анализа монокристала, Раманска спектроскопија, инфрацрвена спектроскопија, водоничне везе, хидрогенарсенати земноалкалних металаTamara Đorđević, Ljiljana Karanović. "A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra" in Journal of Solid State Chemistry, Elsevier BV (2010). https://doi.org/10.1016/j.jssc.2010.09.027 М22
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Malathion-induced inhibition of human plasma cholinesterase studied by the fluorescence spectroscopy method
The in vitro effect of technical grade malathion was assessed via the kinetic parameters of human plasma butyrylcholinesterase (BChE) using N-methylindoxyl acetate as a substrate for BChE. An inhibitor kinetics study demonstrated the existence of a biphasic inhibition curve, indicating high- and low-affinity binding sites of malathion. The IC50 values as calculated from the experimental inhibition curves were 1.33 × 10–9 and 1.48 × 10–5 M for the high- and low-affinity binding sites, respectively; Hill’s analysis gave 1.29 × ...V. M. Pavelkić, K. S. Krinulović, J. Z. Savić, M. A. Ilić. "Malathion-induced inhibition of human plasma cholinesterase studied by the fluorescence spectroscopy method" in Russian Journal of Physical Chemistry A, Pleiades Publishing Ltd (2008). https://doi.org/10.1134/S0036024408050312 М23
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Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs
Marija Stojmenović, Neda Nišić, Milan Zunić, Francesco Basoli, Jelena Gulicovki, Ivica Ristović, Milan Kragović (2022)Nanodimenzionisana multi-dopirana cerija sa sastavom Ce0.8Nd0.0025Sm0.0025Gd0.005Di0.095I0.095O2-d (CNSDI) kao perspektivni čvrsti jonski provodnik je dobijen modifikovanim glicin-nitratnim postupkom (MGNP) i samopropagirajućom reakcijom na sobnoj temperaturi (SPRT). Presovani peleti oba praha su sinterovani na 1550 °C za 2 h u vazdušnoj atmosferi. Dobijeni sinterovani uzorci su okarakterisani KSRPD, Raman spektroskopijom, FESEM, EDS i EIS metode. Uprkos visokoj temperaturi sinterovanja, KSRPD i FESEM analize uzorci su potvrdili odgovarajuće dimenzije zrna sa strukturom fluorita. Ukupna koncentracija uvedenih dodataka (k = 0,2) u strukturi ...Marija Stojmenović, Neda Nišić, Milan Zunić, Francesco Basoli, Jelena Gulicovki, Ivica Ristović, Milan Kragović. "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs" in Processing and Application of Ceramics, National Library of Serbia (2022). https://doi.org/10.2298/PAC2204391S М23
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Human Hemoglobin and Antipsychotics Clozapine, Ziprasidone and Sertindole: Friends or Foes?
Lena Platanić Arizanović, Nikola Gligorijević, Ilija Cvijetić, Aleksandar Mijatović, Maja Krstić Ristivojević, Simeon Minić, Aleksandra Nikolić Kokić, Čedo Miljević, Milan Nikolić (2023)Packed with hemoglobin, an essential protein for oxygen transport, human erythrocytes are a suitable model system for testing the pleiotropic effects of lipophilic drugs. Our study investi gated the interaction between antipsychotic drugs clozapine, ziprasidone, sertindole, and human hemoglobin under simulated physiological conditions. Analysis of protein fluorescence quenching at different temperatures and data obtained from the van’t Hoff diagram and molecular docking indicate that the interactions are static and that the tetrameric human hemoglobin has one binding site for ...Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Computer Science Applications, Spectroscopy, Molecular Biology, General Medicine, CatalysisLena Platanić Arizanović, Nikola Gligorijević, Ilija Cvijetić, Aleksandar Mijatović, Maja Krstić Ristivojević, Simeon Minić, Aleksandra Nikolić Kokić, Čedo Miljević, Milan Nikolić. "Human Hemoglobin and Antipsychotics Clozapine, Ziprasidone and Sertindole: Friends or Foes?" in International Journal of Molecular Sciences, MDPI AG (2023). https://doi.org/10.3390/ijms24108921 М21
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Синтеза и карактеризација керамике на бази сфена
Jelena R. Pantić (2015-07-10)Механохемијска активација стехиометријске смеше реактаната TiO2, SiO2 и CaCO3 показала се као веома успешна и једноставна метода за добијање сфена (CaTiSiO5). На основу мерења релативних густина свих синтерованих узорака установљено је да максималну густину од 93,9 % имају узорци који су активирани 30 минута и синтеровани на 1200 °С. Микроструктурном анализом, тј. анализом слика синтерованих узорака активираних 30 минута, које су добијене скенирајућом електронском микроскопијом, опажа се бимодална расподела величине зрна, са просечном величином од 3 μm, односно 5 ...сфен, механохемија, Ритвелдова метода, оптичка спектроскопија, микроструктурна анализа, фазна трансфоpмација, чврсти раствориJelena R. Pantić. "Синтеза и карактеризација керамике на бази сфена" in Универзитет у Београду, Универзитет у Београду, Рударско-геолошки факултет (2015-07-10)
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Novel cerium and praseodymium doped phosphate tungsten bronzes: Synthesis, characterization, the behavior in the Briggs-Rauscher reaction and photoluminescence properties
Tijana Maksimović, Pavle Tančić, Jelena Maksimović, Dimitrije Mara, Marija Ilić, Rik Van Deun, Ljubinka Joksović, Maja Pagnacco (2023)Due to the interesting and potentially useful properties, phosphate tungsten bronzes are constantly being studied and attract a lot of attention. In the present work, two different metallic elements, belonging to the group of rare-earth metals, cerium and praseodymium, were used as a dopants for phosphate tungsten bronzes. Novel cerium and praseodymium doped phosphate tungsten bronzes were successfully synthesized and further characterized by thermal analyses, Fourier-transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscopy with energy-dispersive X-ray spectrometer and ...Electrical and Electronic Engineering, Atomic and Molecular Physics and Optics, Electronic, Optical and Magnetic Materials, Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, SpectroscopyTijana Maksimović, Pavle Tančić, Jelena Maksimović, Dimitrije Mara, Marija Ilić, Rik Van Deun, Ljubinka Joksović, Maja Pagnacco. "Novel cerium and praseodymium doped phosphate tungsten bronzes: Synthesis, characterization, the behavior in the Briggs-Rauscher reaction and photoluminescence properties" in Optical Materials, Elsevier BV (2023). https://doi.org/10.1016/j.optmat.2023.114125 М22
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Three new Sr-bearing arsenates, hydrothermally synthesized in the system SrO–MO–As2O5–H2O (M2+ = Mg, Cu, Zn)
Tamara Đorđević, Ljiljana Karanović (2018)During systematic research on the mineral-related synthetic arsenates, with particular focus on their structural and spectroscopic classification, three new Sr-containing arsenates Sr2Mg(AsO4)2· 2H2O (1), Sr2Zn4(AsO4)4·H2O (2) and Sr2Cu7(AsO4)6 (3) have been synthesized under low-temperature hydrothermal conditions in the system SrO MO As2O5 H2O (M 2þ = Mg, Zn, Cu). Their crystal structures were determined using room-temperature single-crystal X-ray diffraction data and refined to the following R-values: 1– R1 = 0.025; 2– R1 = 0.030; 3– R1 = 0.035. Compounds ...стронцијум, арсен, арсенати, кристална структура, дифракција рендгенских зрака на монокристалима, хидротермална синтеза, Раманска спектроскопијаTamara Đorđević, Ljiljana Karanović. "Three new Sr-bearing arsenates, hydrothermally synthesized in the system SrO–MO–As2O5–H2O (M2+ = Mg, Cu, Zn)" in European Journal of Mineralogy, Schweizerbart (2018). https://doi.org/10.1127/ejm/2018/0030-2749 М22