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Упит dcterms_subject_txt:Geochemistry and Petrology

2451 items

  • Equilibrium and kinetic studies of the reactions between [Ru(terpy)(bipy)Cl]Cl complex and biologically important N-donor ligands

    Aleksandar Mijatović, Biljana Petrović, Ratomir Jelić, Živadin Bugarčić (2011)
    Studije u oblasti antikancerogenih karakteristika jedinjenja rutenijuma(III/II) izazivaju veliku pažnju već nekoliko godina otkako su neka od njih kao što su KP1019 (indazolijum-tetrahloridobis(H-indazol)rutenat(III)) i NAMI-A (imidazolijum) -trans-tetrahlorido(dimetilsulfoksid)indazolerutenat(III)) dostigao nivo kliničkog ispitivanja. Kompleksi rutenijuma u ​​reakciji sa molekulom DNK formiraju prvenstveno gvanin- i adenin-adukt, kao komplekse platine. Takođe, nekoliko studija ukazuje na veoma jake interakcije sa proteinima. Međutim, kompleksi Ru(III/II) pokazuju generalno manje toksične efekte od lekova platine(II).1 Proučavali smo kinetiku reakcija supstitucije kompleksa [Ru(terpi)(bipi)Cl]Cl sa biološki važnim ligandima: dimetilsulfoksidom, gvanozin-5’-monofosfatom, ...
    ... image1.png Equilibrium and kinetic studies of the reactions between [Ru(terpy)(bipy)Cl]* complex and biologically important N-donor ligands Aleksandar Mijatovié,** Biljana Petrovi¢,* Ratomir Jeli¢,® and Zivadin Bugar¢cic* “Faculty of Science, University of Kragujevac ...
    ... de, | guanosine-S’-monophosphate, thiourea and L-histidine. All reactions were studied by UV-VIS spectrophotometry in 0.1 M NaClO, with 10 mM NaCl. The excess of ligand concentration was used to observed pseudo-first order conditions. The rate constants and activation parameters are calculated using ...
    ... using computational program Origin 6.1. Also we investigated the hydrolysis and complexation reactions of Ru(II) complex with guanosine-5’-monophosphate and L- histidine. Potentiometric titrations were carried out at 298 K in inert atmosphere using a glass electrode. For the calculations is used computation ...

  • Waste rocks and medieval slag as sources of environmental pollution in the area of the Pb-Zn Mine Rudnik (Serbia)

    Alena Zdravković, Vladica Cvetković, Kristina Šarić, Aleksandar Pačevski, Aleksandra Rosić, Suzana Erić (2020)
    The new geochemical and mineralogical data of soil and water from the Pb-Zn Rudnik Mine area (central Serbia) reveal that the areas close to the mining sites and those located remotely from them are both affected by significant pollution by toxic elements, especially As, Pb, Ni and Cr. We, therefore, propose that two main sources are generally responsible for the current state of pollution in this area. The first is the material from waste rock dumps (WRDs) in which ...
    распадање сулфида, микроелементи, пиротин, загађење земљишта, Рударска активност, распадање шљаке

  • Novi pristup proučavanju tekstura minerala značajnih za istraživanje rudnih ležišta

    Aleksandar Pačevski (2022)
    ... enabled a further shift in the study of minerals and their textures to nanometer and even atomic levels, which certainly offers great opportunities, but at the mean time makes a research very complex. Scanning and Transmission Electron Microscopy (SEM and TEM) methods in combination with Electron Microprobe ...
    ... Mining and Geology, Belgrade, Serbia, E-mail: aleksandar.pacevski(ergf.bg.ac.rs Key words: texture, ore, microanalysis, pyrite The complete determination of a mineral composition and textural characteristics of the ores is crucial for correct interpretation of the ore-forming processes and genesis ...
    ... on a micrometer scale, and thus provide significantly more data important for investigating not only deposit genesis, but also possibilities and efficiency of their exploitation. With the development of polarized light microscopy as the basic methods of minerals, ores and rocks study, numerous textural ...

  • Long-term rockslope monitoring and rockfall prediction

    Miloš Marjanović, Biljana Abolmasov, Marko Pejić, Jelka Krušić (2021)
    ... traffic interruption; property damage; river damming and secondary floods and landslides. Dealing with rockfalls is a major topic for decision-makers and engineers, targeted at answering where and when will rockfalls occur and what preventive and remediation measures should be undertaken to neutralize ...
    ... monitoring and proved to be one of the most efficient and most robust approaches. It is based on change detection of point clouds, collected in sequences, annually or more frequently, depending on the slope’s dynamics. Each new point cloud can be compared against any of the previous, and all detectable ...
    ... 2024-12-25 10:42:36 Long-term rockslope monitoring and rockfall prediction Miloš Marjanović, Biljana Abolmasov, Marko Pejić, Jelka Krušić Дигитални репозиторијум Рударско-геолошког факултета Универзитета у Београду [ДР РГФ] Long-term rockslope monitoring and rockfall prediction | Miloš Marjanović, Biljana ...

  • Projected changes in air temperature, precipitation and aridity in Serbia in the 21st century

    Boško Milovanović, Sebastian Schubert, Milan Radovanović, Vesna Ristić Vakanjac, Christoph Schneider (2021)
    У овој студији се испитују пројектоване промене средњих месечних и годишњих температура ваздуха, количине падавина и Де Мартоновог индекса аридности у Србији у 21. веку. У ту сврху статистички је моделована просторна дистрибуција температуре ваздуха и количине падавина на основу података 64 климатолошке станице и 421 падавинске станице за период 1976–2005 применом вишеструке линеарне регресије. Де Мартонов индекс аридности се израчунава из просторно распоређених података. Да бисмо добили регионалне просеке и варијабилност, Србију делимо на три поддомена: западну зону ...
    21 век, температуре ваздуха, климатске промене, Де Мартонеов индекс аридности, падавине, Србија

  • Synthesis, characterization, biomolecular interactions, molecular docking, and in vitro and in vivo anticancer activities of novel ruthenium(III) Schiff base complexes

    Milica Međedović, Aleksandar Mijatović, Rada Baošić, Dejan Lazić, Žiko Milanović, Zoran Marković, Jelena Milovanović, Dragana Arsenijević, Bojana Stojanović, Miloš Arsenijević, Marija Milovanović, Biljana Petrović, Ana Rilak Simović (2023)
    In order to discover new anticancer drugs, novel ruthenium(III) complexes [Ru(L)Cl(H2O)], where L is tetradentate Schiff base bis(acetylacetone)ethylendiimine (acacen, 1), bis(benzoylacetone)ethylendiimine (bzacen, 2), (acetylacetone)(benzoylaceton)ethylendiimine (acacbzacen, 3), bis(acetylacetone)propylendiimine (acacpn, 4), bis(benzoylacetone)propylendiimine (bzacpn, 5) or (acetylacetone)(benzoylaceton)propylendiimine (acacbzacpn, 6), were synthesized. The complexes 1 – 6 were characterized by elemental analysis, molar conductometry, and by various spectroscopic techniques, such as UV–Vis, IR, EPR, and ESI-MS. Based on in vitro DNA/BSA experiments, complexes 2 (bzacen) and 5 (bzacpn) with two aromatic rings showed ...
    Inorganic Chemistry, Biochemistry

  • Sitni, ali bitni: uloga sitnih sisara, herpetofaune i mekušaca u rekonstrukciji pleistocenskih paleosredina

    Katarina Bogićević, Draženko Nenadić, Dragana Đurić, Mihajlo Jovanović, Aleksandra Savković (2023)
    Fosilni ostaci životinja i biljaka imaju važnu ulogu u rekonstrukciji pleistocenskih paleosredina. U ovom radu opisan je značaj tri grupe životinja: sitnih sisara, herpetofaune I mekušaca. Mada je za rekonstrukciju važan sastav čitave asocijacije, nalasci pojedinih vrsta mogu biti dovoljno indikativni da otkriju tip staništa ili klimatske uslove. Posebnu teškoću pri rekonstrukciji paleosredina u Srbiji predstavlja činjenica da klimatske promene na Balkanskom poluostrvu nisu bile tako oštre kao u srednjoj i zapadnoj Evropi, pa ne postoji drastična razlika u ...
    ... & Bogićević, K., (2016): Technological changes and population movements in the late Lower and carly Middle Palaeolithic of the Central Balkans. In: K. Harvati & M. Roksandić (Eds.), Paleoanthropology of the Balkans and Anatolia: Human evolution and its context, Dordrecht: Springer, 139-151. 6. ...
    ... that indicate marshy, river and lake environments or are in question forms that are exclusively related to loess and terrestrial living conditions, etc. Conclusion: The use of small vertebrates and molluscs in the reconstruction of palaeoenvironmental conditions and palaeoclimate is only in its ...
    ... based up on fossil remains of amphibians and reptiles of the Late Cenozoic of the East European platform. Paleontological Journal, 1, 75—80. 8. Ratnikov, V.Yu., (2016): Dynamics of East European modern amphibians and rceptiles species distribution areas and thcir potential use in Quaternary stratigraphy ...

  • Dynamic and Static Elastic Properties - Laboratory Investigations of Metamorphites of the "Vranjska Banja" Series

    Jelena Majstorović, Bojan Dimitrijević, Suzana Lutovac, Snežana Savković, Miloš Gligorić (2021)
    Metamorphites of the series “Vranjska banja” built predominantly of high crystallinity schist series, alternately layered double mica, gneiss, leptonite and micaschist. For the construction of the “Prvonek” dam were carried out laboratory investigations of dynamic and static elastic properties on micashist and gneiss samples in the perpendicular and parallel direction to the foliation. These investigations provided monitoring of the rock mass anisotropy properties and greater reliability of the design parameteres. As the design of mining and construction facilities becomes ...
    micashist, gneiss, foliation, dynamic properties, static properties

  • Numerical modelling of the roughly simultaneous emplacement of two distinct ophiolite belts

    Nikola Stanković, Vesna Cvetkov, Vladica Cvetković (2024)

  • Transboundary groundwater resources of Serbia - present status and future needs for sustainable management

    Veljko Marinović, Branislav Petrović, Zoran Stevanović (2021)
    Republic of Serbia is located at the crossroads of Southeast and Central Europe and belongs to the Central Balkans. With its 88,360 km2, Serbia is one of the larger countries of the Balkan Peninsula. It borders 8 countries and has at least one transboundary aquifer (TBA) with each of them. According to evaluation conducted for UNECE in 2008, Serbia has a total of 17 TBAs, out of which 15 are shared with one neighboring country, while two aquifers are shared with two or three ...
    međugranične izdani, Srbija, monitoring podzemnih voda, upravljanje podzemnim vodama

  • Influence of geological substrate on runoff formation, a case study: small river catchments in southeastern Serbia of similar size and with comparable pluviographic regimes

    Vesna Ristić Vakanjac, Veljko Marinović, Nikola Milovanović, Marina Čokorilo Ilić, Boris Vakanjac, Jugoslav Nikolić, Saša Bakrač (2022)
    We are witnessing climate change that is happening both, globally and, at the regionally - or local level. As a result of expected climate change in Southeast Europe, in the first place are the distributions of precipitation within the year (frequent extreme events are present) and then the increase in temperature, which already has a significant impact on evapotranspiration and runoff formed in a particular catchment area. In addition to climatic factors, the geological structure, i.e. the hydrogeological characteristics ...

  • Application of auto-cross-regression models from the shortterm forecast of karst spring discharges

    Vesna Ristić Vakanjac, Veljko Marinković, Ljiljana Vasić, Saša Milanović, Branislav Petrović, Petar Vojnović (2024)
    Човек je одвајкада је покушавао да пронађе начина да предвиди одређене појаве у природи. Како су људске насеобине углавном биле везане за обале река, предикција поплаве је била од великог значаја за њен опстанак. Касније, развојем цивилизације, а нарочито са индустријском и технолошком револуцијом, отпочиње се са развојем одређених модела којима се на основу улазних компоненти срачунава излазна величина која је од интереса, а у овом случају је то протицај или водостај реке или извора (врела). Најједноставнији модели су ...
    режим, карстно врело, истицање, аутокросрегресиони модел

  • The shear strength evaluation of rough and infilled joints and its indications for stability of rock cutting in schist rock mass

    Dušan Berisavljević, Zoran Berisavljević, Svetlana Melentijević (2022)
    Construction of E75 highway section through Grdelica gorge was one of the most demanding projects realized in recent Serbian history. The alignment approximately 25 km long consists of several tens of bridges, two tunnels, three galleries and cuts with total length of 6 km. The alignment passes through highly anisotropic Palaeozoic schist rock formation of different weathering grades. This study focuses on shear strength properties of discontinuities, which are found to be the critical feature contributing to the occurrence ...
    Diskontinuitet, nelinearni kriterijum loma, anizotropija, hiperbolična anvelopa

  • Overview of the hydrogeological investigations of recently discovered world class deposits in Serbia

    Nebojša Atanacković, Vladimir Živanović, Veselin Dragišić, Sava Magazinović (2019)
    Europe industry has growing concerns on availability of the raw materials. To address this challenge, the European Commission has created a list of critical raw materials for the EU, launched EIT Raw Materials initiative, and continuously support research projects (like INTRAW, UNEXMIN etc.) with the aim of reducing the dependency and meeting growing demands. In the last 15 years Serbia is experiencing new bust in geological exploration of mineral deposits. Currently 167 exploration licenses are active, covering approximately 6000 ...
    Groundwater, Raw materials, Lithium, Mining, Field hydrogeology

  • Development and Application of Methodology for Quantification of Overbreaks in Hard Rock Tunnel Construction

    Zoran Berisavljević, Dragoljub Bajić, Vojkan Jovičić (2023)
    A methodology for determining overbreaks in hard rock tunnel construction using the drill-and-blast technique is presented in this paper. The methodology was developed for and applied to crystalline medium- to thick-bedded limestone, but it can be used in any jointed hard rock mass. Overbreaks are inevitable in hard rock tunnelling in a low-confinement environment (shallow tunnels up to several hundred meters deep) as a result of wedge failures along unfavourably oriented discontinuities caused by blasting. It is widely accepted ...
    hard rock, drill-and-blast, geological overbreak, technological overbreak, stability criterion, discontinuity orientation, tunnel construction

  • Application of cross-correlation analysis of karst spring discharges with the purpose of understanding karst hydrogeology systems

    Veljko Marinković, Vesna Ristić Vakanjac, Saša Milanović, Ljiljana Vasić, Branislav Petrović, Petar Vojnović (2024)
    Када посматрамо одређену издан, прихрањивање подземних вода ове издани се може вршити 1. на рачин падавина, 2. на рачун површинских токова у деловима где постоји добра хидрауличка веза подземних и површинских вода и где је ниво површинског тока на вишој коти од нивоа подземних вода, или понирањем површинских вода, и 3. на рачун подземних вода других типова издани. Код издани формираних у оквиру карстних масива, прихрањивање ових вода најчешће се врши инфитрацијом падавина и понирањем површинских токова тамо где ...
    режим, карстно врело, истицање, кроскорелација, Ријека Црнојевића врело

  • Pannonian Basin, Pannonian Basin System and Pannonian realm - three different concepts

    Dejan Radivojević (2019)
    Centralni Paratetis, neogen, Panonski basen, Sistem panonskog basena, Panonska oblast

  • An optimal sixteenth order family of methods for solving nonlinear equations and their basins of attraction

    Dejan Ćebić, Nebojša Ralević, Marina Marčeta (2020)
    нелинеарна једначина, 16.ред конвергенције, оптималне методе, подељене разлике
    ... sufficiently differentiable in a neighbor- hood of its simple root α, and let M4(·, ·) and M8(·, ·, ·) be any optimal fourth and eighth order methods based on Newton’s method, satisfying zn − α = 16 ∑ i=4 Bie i n +O(e17n ) (2) and yn − α = 16 ∑ i=8 Aie i n +O(e17n ), (3) An optimal sixteenth ...
    ... 24] and optimal eighth order methods [2, 3, 5, 8, 9, 10, 17, 22, 27, 31, 32, 36] whose indices are 1.5874 and 1.6818, respectively. Although in further analysis this study will be concerned only with the optimal sixteenth order methods and their comparisons, several optimal methods of fourth and eighth ...
    ... − xn, s3 = wn − xn and f [t, x, x] = f [tn, xn]− f ′(xn) tn − xn . For the interpretation of the numerical behaviour and computational efficiency of the proposed methods, we have used test examples and appropriate initial approxima- tions displayed in Table 2. Functions f1, f2 and f3 are derived from ...

  • Strategic Environmental Assessment and the precautionary principle in the spatial planning of wind farms – European experience in Serbia

    Boško Josimović, Aleksandar Cvjetić, Danilo Furundžić (2021)
    Spatial determination planning is at an initial and very sensitive step in the development of wind farms. On one hand, it is important to maximize the potential of wind in a particular area, and on the other hand, it is important to achieve environmental protection (including the human population and natural heritage) in the same space at the same time. With this in mind, it is important to balance all the requirements that are relevant for reaching the optimal ...
    Obnovljiva energija, Održivost, Životna sredina

  • The Flow Conditions in the Epikarst Zone of a Karst Aquifer. Case Study: Suva planina Mt., East Serbia

    Branislav Petrović (2023)
    The epikarst as a part of the karst aquifer represents a complex point of contact and mixing of unconsolidated material from the terrain surface, carbonate rocks altered by “corrosive” water, flora and fauna (and remains of), which is partially saturated with groundwater. Significant amounts of (plant accessible) water, and other solutes and particles, can be stored in this zone for extended periods of time. Thus, attenuation or biochemical processes could start in this layer and change quality of infiltrated ...
    epikarst, tracer test, shallow cave, Suva Planina Mt., Serbia